Industrial photochemistry XXIV. Relations between light flux and polymerized depth in laser stereophotolithography
Identifieur interne : 002088 ( Main/Exploration ); précédent : 002087; suivant : 002089Industrial photochemistry XXIV. Relations between light flux and polymerized depth in laser stereophotolithography
Auteurs : P. Schaeffer [France] ; A. Bertsch [France] ; S. Corbel [France] ; J. Y. Jézéquel [France] ; J. C. André [France]Source :
- Journal of Photochemistry & Photobiology, A: Chemistry [ 1010-6030 ] ; 1997.
Descripteurs français
- Pascal (Inist)
- Wicri :
- topic : Photochimie.
English descriptors
- KwdEn :
- Better resolution, Circular symmetry, Different layers, Different values, Direct measurement, Empirical laws, Experimental measurements, Experimental results, Experimental study, First approximation, Gaussian, Gaussian distribution, Gaussian light flux distribution, Gaussian mode, Good agreement, Hydrodynamic forces, Incident light flux, Industrial application, Initiator concentration, Irradiation power, Irradiation power increases, Irradiation time, Laser, Laser beam, Laser beam power, Laser mode, Laser power, Laser stereophotolithography, Layer thickness, Light beam, Light flux, Light flux distribution, Light penetration depth, Liquid monomer, Liquid reactive medium, Liquid resin, Microelectronic fabrication, Numerical determination, Optical thickness, Paraboloidal shape, Photobiology, Photochemistry, Photoinitiator, Photoinitiator concentration, Photolithography, Photopolymerizable resin, Polymerization, Polymerization reaction, Polymerization resolution, Polymerized, Polymerized depth, Polymerized part, Polymerized point, Polymerized threads, Polymerized volume, Polymerized width, Reactive, Reactive medium, Scanning, Scanning speed, Scanning speeds, Schaeffer, Simplified model, Solid polymer, Standardized measurement, Standardized method, Standardized test, Straight lines, Surface roughness, Three dimensional structure.
- Teeft :
- Better resolution, Circular symmetry, Different layers, Different values, Direct measurement, Empirical laws, Experimental measurements, Experimental results, First approximation, Gaussian, Gaussian distribution, Gaussian light flux distribution, Gaussian mode, Good agreement, Hydrodynamic forces, Incident light flux, Initiator concentration, Irradiation power, Irradiation power increases, Irradiation time, Laser, Laser beam, Laser beam power, Laser mode, Laser power, Laser stereophotolithography, Layer thickness, Light beam, Light flux, Light flux distribution, Light penetration depth, Liquid monomer, Liquid reactive medium, Liquid resin, Numerical determination, Optical thickness, Paraboloidal shape, Photobiology, Photochemistry, Photoinitiator, Photoinitiator concentration, Photopolymerizable resin, Polymerization reaction, Polymerization resolution, Polymerized, Polymerized depth, Polymerized part, Polymerized point, Polymerized threads, Polymerized volume, Polymerized width, Reactive, Reactive medium, Scanning, Scanning speed, Scanning speeds, Schaeffer, Simplified model, Solid polymer, Standardized measurement, Standardized method, Standardized test, Straight lines, Surface roughness.
Abstract
Abstract: The stereophotolithography process allows a three-dimensional object to be built by layer-by-layer, space-resolved, light-induced polymerization of a liquid monomer into a solid polymer. The relationship between the light penetration depth in the photoreacting medium, the scanning speed of the laser beam on the surface of the resin and the laser power has been studied. Experimental measurements have been performed and compared with a kinetic model. Empirical laws of evolution of the polymerized depth vs. macroscopic parameters have also been determined allowing the optimal operating conditions in stereophotolithography to be defined.
Url:
DOI: 10.1016/S1010-6030(97)00062-2
Affiliations:
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Corbel</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>DCPR (GRAPP) URA 328 and GdR 1080 CNRS, ENSIC-INPL, 1 rue Grandville, BP 451, F-54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author><author><name sortKey="Jezequel, J Y" sort="Jezequel, J Y" uniqKey="Jezequel J" first="J. Y." last="Jézéquel">J. Y. Jézéquel</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>DCPR (GRAPP) URA 328 and GdR 1080 CNRS, ENSIC-INPL, 1 rue Grandville, BP 451, F-54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation></author><author><name sortKey="Andre, J C" sort="Andre, J C" uniqKey="Andre J" first="J. C." last="André">J. C. André</name><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>DCPR (GRAPP) URA 328 and GdR 1080 CNRS, ENSIC-INPL, 1 rue Grandville, BP 451, F-54001 Nancy Cedex</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Nancy</settlement></placeName></affiliation><affiliation wicri:level="3"><country xml:lang="fr">France</country><wicri:regionArea>INRS, Direction Etudes et Recherches, Avenue de Bourgogne, F-54500 Vandoeuvre</wicri:regionArea><placeName><region type="region" nuts="2">Grand Est</region><region type="old region" nuts="2">Lorraine (région)</region><settlement type="city">Vandoeuvre</settlement></placeName></affiliation></author></analytic><monogr></monogr><series><title level="j">Journal of Photochemistry & Photobiology, A: Chemistry</title><title level="j" type="abbrev">JPC</title><idno type="ISSN">1010-6030</idno><imprint><publisher>ELSEVIER</publisher><date type="published" when="1997">1997</date><biblScope unit="volume">107</biblScope><biblScope unit="issue">1–3</biblScope><biblScope unit="page" from="283">283</biblScope><biblScope unit="page" to="290">290</biblScope></imprint><idno type="ISSN">1010-6030</idno></series></biblStruct></sourceDesc><seriesStmt><idno type="ISSN">1010-6030</idno></seriesStmt></fileDesc><profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Better resolution</term><term>Circular symmetry</term><term>Different layers</term><term>Different values</term><term>Direct measurement</term><term>Empirical laws</term><term>Experimental measurements</term><term>Experimental results</term><term>Experimental study</term><term>First approximation</term><term>Gaussian</term><term>Gaussian distribution</term><term>Gaussian light flux distribution</term><term>Gaussian mode</term><term>Good agreement</term><term>Hydrodynamic forces</term><term>Incident light flux</term><term>Industrial application</term><term>Initiator concentration</term><term>Irradiation power</term><term>Irradiation power increases</term><term>Irradiation time</term><term>Laser</term><term>Laser beam</term><term>Laser beam power</term><term>Laser mode</term><term>Laser power</term><term>Laser stereophotolithography</term><term>Layer thickness</term><term>Light beam</term><term>Light flux</term><term>Light flux distribution</term><term>Light penetration depth</term><term>Liquid monomer</term><term>Liquid reactive medium</term><term>Liquid resin</term><term>Microelectronic fabrication</term><term>Numerical determination</term><term>Optical thickness</term><term>Paraboloidal shape</term><term>Photobiology</term><term>Photochemistry</term><term>Photoinitiator</term><term>Photoinitiator concentration</term><term>Photolithography</term><term>Photopolymerizable resin</term><term>Polymerization</term><term>Polymerization reaction</term><term>Polymerization resolution</term><term>Polymerized</term><term>Polymerized depth</term><term>Polymerized part</term><term>Polymerized point</term><term>Polymerized threads</term><term>Polymerized volume</term><term>Polymerized width</term><term>Reactive</term><term>Reactive medium</term><term>Scanning</term><term>Scanning speed</term><term>Scanning speeds</term><term>Schaeffer</term><term>Simplified model</term><term>Solid polymer</term><term>Standardized measurement</term><term>Standardized method</term><term>Standardized test</term><term>Straight lines</term><term>Surface roughness</term><term>Three dimensional structure</term></keywords><keywords scheme="Pascal" xml:lang="fr"><term>Application industrielle</term><term>Etude expérimentale</term><term>Fabrication microélectronique</term><term>Photochimie</term><term>Photolithographie</term><term>Polymérisation</term><term>Structure 3 dimensions</term></keywords><keywords scheme="Teeft" xml:lang="en"><term>Better resolution</term><term>Circular symmetry</term><term>Different layers</term><term>Different values</term><term>Direct measurement</term><term>Empirical laws</term><term>Experimental measurements</term><term>Experimental results</term><term>First approximation</term><term>Gaussian</term><term>Gaussian distribution</term><term>Gaussian light flux distribution</term><term>Gaussian mode</term><term>Good agreement</term><term>Hydrodynamic forces</term><term>Incident light flux</term><term>Initiator concentration</term><term>Irradiation power</term><term>Irradiation power increases</term><term>Irradiation time</term><term>Laser</term><term>Laser beam</term><term>Laser beam power</term><term>Laser mode</term><term>Laser power</term><term>Laser stereophotolithography</term><term>Layer thickness</term><term>Light beam</term><term>Light flux</term><term>Light flux distribution</term><term>Light penetration depth</term><term>Liquid monomer</term><term>Liquid reactive medium</term><term>Liquid resin</term><term>Numerical determination</term><term>Optical thickness</term><term>Paraboloidal shape</term><term>Photobiology</term><term>Photochemistry</term><term>Photoinitiator</term><term>Photoinitiator concentration</term><term>Photopolymerizable resin</term><term>Polymerization reaction</term><term>Polymerization resolution</term><term>Polymerized</term><term>Polymerized depth</term><term>Polymerized part</term><term>Polymerized point</term><term>Polymerized threads</term><term>Polymerized volume</term><term>Polymerized width</term><term>Reactive</term><term>Reactive medium</term><term>Scanning</term><term>Scanning speed</term><term>Scanning speeds</term><term>Schaeffer</term><term>Simplified model</term><term>Solid polymer</term><term>Standardized measurement</term><term>Standardized method</term><term>Standardized test</term><term>Straight lines</term><term>Surface roughness</term></keywords><keywords scheme="Wicri" type="topic" xml:lang="fr"><term>Photochimie</term></keywords></textClass><langUsage><language ident="en">en</language></langUsage></profileDesc></teiHeader><front><div type="abstract" xml:lang="en">Abstract: The stereophotolithography process allows a three-dimensional object to be built by layer-by-layer, space-resolved, light-induced polymerization of a liquid monomer into a solid polymer. The relationship between the light penetration depth in the photoreacting medium, the scanning speed of the laser beam on the surface of the resin and the laser power has been studied. Experimental measurements have been performed and compared with a kinetic model. Empirical laws of evolution of the polymerized depth vs. macroscopic parameters have also been determined allowing the optimal operating conditions in stereophotolithography to be defined.</div></front></TEI><affiliations><list><country><li>France</li></country><region><li>Grand Est</li><li>Lorraine (région)</li></region><settlement><li>Nancy</li><li>Vandoeuvre</li></settlement></list><tree><country name="France"><region name="Grand Est"><name sortKey="Schaeffer, P" sort="Schaeffer, P" uniqKey="Schaeffer P" first="P." last="Schaeffer">P. Schaeffer</name></region><name sortKey="Andre, J C" sort="Andre, J C" uniqKey="Andre J" first="J. C." last="André">J. C. André</name><name sortKey="Andre, J C" sort="Andre, J C" uniqKey="Andre J" first="J. C." last="André">J. C. André</name><name sortKey="Bertsch, A" sort="Bertsch, A" uniqKey="Bertsch A" first="A." last="Bertsch">A. Bertsch</name><name sortKey="Corbel, S" sort="Corbel, S" uniqKey="Corbel S" first="S." last="Corbel">S. Corbel</name><name sortKey="Jezequel, J Y" sort="Jezequel, J Y" uniqKey="Jezequel J" first="J. Y." last="Jézéquel">J. Y. Jézéquel</name><name sortKey="Schaeffer, P" sort="Schaeffer, P" uniqKey="Schaeffer P" first="P." last="Schaeffer">P. Schaeffer</name></country></tree></affiliations></record>Pour manipuler ce document sous Unix (Dilib)
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